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Question

Chemistry Question on Equilibrium

106MNaOH10^{-6}\, M\, NaOH is diluted 100100 times. The pHpH of the diluted base is

A

between 6 and 7

B

between 10 and 11

C

between 7 and 8

D

between 5 and 6

Answer

between 7 and 8

Explanation

Solution

[OH]\left[ OH ^{-}\right] in the diluted base =106102=108=\frac{10^{-6}}{10^{2}}=10^{-8}

Total [OH]=108+[OH]\left[ OH ^{-}\right]=10^{-8}+\left[ OH ^{-}\right] of water

=(108+107)M=\left(10^{-8}+10^{-7}\right)\,M
=108[1+10]M=10^{-8}[1+10]\, M
=11×108M=11 \times 10^{-8} M
pOH=log11×108pOH =-\log 11 \times 10^{-8}
=log11+8log10=-\log 11+8 \log 10
=6.9586=6.9586
pH=146.9586pH =14-6.9586
=7.0414=7.0414