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Question: 1 mole of an ideal gas in a cylindrical container have the P-V diagram as shown in figure. If V2 = 4...

1 mole of an ideal gas in a cylindrical container have the P-V diagram as shown in figure. If V2 = 4V1, then the ratio of temperatures will be

A

12\frac { 1 } { 2 }

B

14\frac { 1 } { 4 }

C

32\frac { 3 } { 2 }

D

34\frac { 3 } { 4 }

Answer

12\frac { 1 } { 2 }

Explanation

Solution

: Ideal gas equation,

PV=nRTP V = n R T Or T=PVnRT = \frac { P V } { n R }….. (i)

According to question

PV1/2=P V ^ { 1 / 2 } = constant (1)

Multiplying both side by V\sqrt { V }

Or PV=AVP V = A \sqrt { V }….. (ii)

Form equation (i) and (ii)

T=AVnRTV\therefore T = \frac { A \sqrt { V } } { n R } \Rightarrow T \propto \sqrt { V }

Now T1T2=V1V2=V14V1=12[V2=4V1]\frac { T _ { 1 } } { T _ { 2 } } = \sqrt { \frac { V _ { 1 } } { V _ { 2 } } } = \sqrt { \frac { V _ { 1 } } { 4 V _ { 1 } } } = \frac { 1 } { 2 } \quad \left[ \because V _ { 2 } = 4 V _ { 1 } \right]

T1T2=12\therefore \frac { T _ { 1 } } { T _ { 2 } } = \frac { 1 } { 2 }