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Question: A vertical cylinder of height 100 cm contains air at a constant temperature. The top is closed by a ...

A vertical cylinder of height 100 cm contains air at a constant temperature. The top is closed by a frictionless light piston. The atmospheric pressure is equal to 75 cm of mercury. Mercury is slowly poured over the piston. Find the maximum height of the mercury column that can be put on the piston.

Answer

Infinite

Explanation

Solution

The problem involves an isothermal compression of air. According to Boyle's Law, P1h1=P2h2P_1h_1 = P_2h_2. Initially, P1=Patm=75P_1 = P_{atm} = 75 cm Hg and h1=100h_1 = 100 cm. When mercury of height hmh_m is added, P2=Patm+hm=75+hmP_2 = P_{atm} + h_m = 75 + h_m. So, 75×100=(75+hm)h275 \times 100 = (75 + h_m)h_2. To maximize hmh_m, h2h_2 must be minimized. For an ideal gas, h2h_2 can approach zero, but never reach it. As h20h_2 \to 0, P2P_2 \to \infty, which implies hmh_m \to \infty. Thus, the maximum height of the mercury column is infinite.