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Question

Chemistry Question on coordination compounds

0.020.02 mole of [Co(NH3)5Br]Cl2[Co(NH_{3})_{5}Br]Cl_{2} and 0.020.02 mole of [Co(NH3)5Cl]SO4[Co(NH_{3})_{5}Cl]SO_{4} are present in 200cc200\, cc of a solution XX. The number of moles of the precipitates YY and ZZ that are formed when the solution XX is treated with excess silver nitrate and excess barium chloride are respectively

A

0.02, 0.02

B

0.01, 0.02

C

0.02, 0.04

D

0.04, 0.02

Answer

0.04, 0.02

Explanation

Solution

[Co(NH3)5Br]1molCl2+2AgNO3\underset{1 mol}{[ Co \left( NH _{3}\right)_{5} Br ]} Cl _{2}+2 AgNO _{3} \longrightarrow

[Co(NH3)5Cl]1molSO4+BaCl2\underset{1 mol}{[Co(NH_{3})_{5}Cl]}SO_{4}+BaCl_{2} \to