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Question: > CN– is oxidised by NO3– in presence of acid : > > a CN– + b NO3– + c H+\(\longrightarrow\) (a + b)...

CN– is oxidised by NO3– in presence of acid :

a CN– + b NO3– + c H+\longrightarrow (a + b) NO + a CO2 + H2O

What are the whole number values of a, b, c in that order :

A

3, 7, 7

B

3, 10, 7

C

3, 10, 10

D

3, 7, 10

Answer

3, 7, 10

Explanation

Solution

(4)

Equating number of O-atoms on both sides :

3b = a + b + 2a + c/2

\therefore 4 b = 6 a + c

Also, from charge balance : c = a + b

\thereforea : b : c = 3 : 7 :10