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Question: > Choose the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are...

Choose the molecular formula of an oxide of iron in which the mass per cent of iron and oxygen are 69.9 and 30.130.1 respectively and its molecular mass is 160.9?

A

FeOFeO

B

Fe3O4Fe_{3}O_{4}

C

Fe2O3Fe_{2}O_{3}

D

FeO2FeO_{2}

Answer

Fe2O3Fe_{2}O_{3}

Explanation

Solution

(3) : For element Fe, mole of atoms = 69.956\frac{69.9}{56}=1.251.25

For element O, mole of atoms = 30.116=1.88\frac{30.1}{16} = 1.88

Mole ratio of Fe =1.251.25=1.= \frac{1.25}{1.25} = 1.

Mole ratio of O =1.881.25=1.5\frac{1.88}{1.25} = 1.5

Simplest whole number ratio of Fe and O = 2, 3

Empirical formula of compound = Fe2O3{Fe}_{2}O_{3}

Molecular mass of Fe2O3Fe_{2}O_{3}=160

n=MolecularmassEmpiricalformulamass=160160=1\frac{Molecularmass}{Empiricalformulamass} = \frac{160}{160} = 1

Molecular formula =Fe2O3= Fe_{2}O_{3}