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Question: > 500 ml of a hydrocarbon gas burnt in excess of oxygen yields 2500 ml of CO2 and 3 lts of water vap...

500 ml of a hydrocarbon gas burnt in excess of oxygen yields 2500 ml of CO2 and 3 lts of water vapours. All volume being measured at the same temperature and pressure. The formula of the hydrocarbon is

A

C5H10

B

C5H12

C

C4H10

D

C4H8

Answer

C5H12

Explanation

Solution

(2)

CxHy + O2 \longrightarrow CO2 + H2O

x×nCxHy=nCO2x \times n_{Cx}H_{y} = n_{CO_{2}} (POAC on C)

x ´ 500 = 2500 (x = 5)

y ´ nCx Hy = 2 ´nH2On_{H_{2}O}

(POAC on H)

y ´ 500 = 2 ´ 3000 y = 12

Formula = C5H12